Technology

Supercritical CO₂, and why it changes the extract.

Carbon dioxide above 73.8 bar and 31.1 °C stops behaving like a gas or a liquid and becomes something in between. It diffuses through plant material like a gas and dissolves oils like a solvent — and when you drop the pressure, it disappears completely.

The principle

A solvent with a dial on it

Hexane is hexane. Its solvating power is fixed, so it takes what it takes and you separate the rest downstream. Supercritical CO₂ is different: its density — and therefore what it will dissolve — changes continuously with pressure and temperature.

That turns solvent selection into a process variable. At lower pressures CO₂ is relatively non-polar and picks up light volatiles and aroma compounds. Push the pressure up and it starts pulling heavier resins, waxes and pigments. We run between 300 and 600 bar at 35–80 °C, choosing the window per crop and per specification.

Practically, this means we can give you a light, aroma-forward essential oil fraction and a heavy, actives-rich oleoresin fraction from the same botanical — or a single full-spectrum extract if that's what your formulation needs.

Operating window

  • CO₂ critical point73.8 bar / 31.1 °C
  • Extraction pressure300 – 600 bar
  • Extraction temperature35 – 80 °C
  • SolventFood-grade CO₂, 100%
  • Co-solventNone used
  • Residual solvent<0.1% CO₂, nothing else

The process

From raw crop to sealed drum

Seven steps, one closed loop. The CO₂ that leaves the separator goes back into the extraction vessel.

Cleaning, drying & grinding

Incoming material is cleaned, dried to a target moisture and milled to a controlled particle size. Particle size drives extraction kinetics more than almost anything else, so this step is specified per crop, not done by eye.

Charging the vessel

Prepared material is charged into the extraction vessel and sealed. Bed packing is controlled to avoid channelling, which is the usual cause of inconsistent yield between batches.

Pressurisation

CO₂ is compressed past its critical point and brought to the target pressure and temperature for that crop and that fraction.

Selective extraction

Supercritical CO₂ flows through the bed, dissolving the target compounds. Contact time and flow rate are set by the recipe for that product.

Fraction separation

The loaded CO₂ passes into separators held at stepped pressures. As pressure falls, solvating power falls, and different fractions precipitate out at different stages — this is where a fraction is isolated rather than blended.

CO₂ recovery

Stripped CO₂ is condensed and returned to the storage tank for the next cycle. Over 90% is recovered, which is both an environmental and a cost story.

Filtration, testing & packing

The extract is filtered, sampled and tested against specification. Once released, it is packed under nitrogen into aluminium-lined bags or HDPE drums with the COA travelling with the consignment.

Plant parameters

What the plant actually runs at

Design and operating parameters. Ginger is quoted as the reference crop; yields and output shift by botanical and fraction.
ParameterValueNote
Finished extract capacityUp to 2 MT/month1–2 tonnes per month depending on crop and fraction
Production modelContinuous campaignTwo-shift operation, 330 days a year
Extraction pressure300 – 600 barSet per crop and per fraction
Extraction temperature35 – 80 °CLow enough to protect thermolabile actives
Solvent100% food-grade CO₂No hexane, ethanol or co-solvent on site
CO₂ recovery>90%Condensed and returned to the loop each cycle
Ginger extract yield5.5%Guaranteed on dried sonth
Minimum trial lotSmall-batchTrial quantities accepted for evaluation
Liquid effluentNilZero liquid discharge

Comparison

CO₂, steam distillation and solvent extraction

Each method has a place. Here's an honest read on where each one lands.

  Supercritical CO₂ Steam distillation Solvent (hexane / ethanol)
Operating temperature35 – 80 °C100 °C+60 – 80 °C, plus desolventising heat
Solvent residueNoneNoneResidual solvent, requires testing and limits
Thermolabile activesPreservedOften degradedPartly degraded during desolventising
Aroma fidelityClose to the fresh plantTop notes lost, cooked characterVariable; solvent character can carry
SelectivityTunable by pressure and temperatureVolatiles onlyBroad, non-selective
Heavy / non-volatile activesAccessible at high pressureNot extractableAccessible
EffluentZero liquid dischargeCondensate to treatSolvent-laden effluent and emissions
Clean-label positionStrongStrongRequires declaration
Capital costHighLowModerate

Steam distillation remains the sensible route for many high-volume, low-value volatile oils. We use CO₂ where the actives are heat-sensitive, where the aroma matters, or where a solvent declaration would cost you the account.

Flexibility

One vessel, many crops

Because the solvent is the same for every product and only the parameters change, the plant switches botanicals without a rebuild. We run in campaigns — a block of days on one crop, then a changeover and cleaning cycle, then the next.

For you, that has two consequences. First, we can take on a botanical we haven't run before without a capital conversation. Second, we can run genuinely small campaigns for a trial — and then scale the same product up to two tonnes a month once it's approved, without changing the process.

Suited to CO₂ extraction

  • Heat-sensitive actives that distillation degrades
  • Aroma-critical materials where top notes matter
  • Products where a solvent declaration is a commercial problem
  • Applications needing a specific fraction, not everything
  • Clean-label, organic and export-facing formulations
  • Botanicals where a resin and a volatile oil are both wanted

Have a botanical you want extracted?

Send us the material and the target profile. We'll run a lab-scale assessment and tell you honestly whether CO₂ is the right route for it.